Produktbild: Organic Chemistry as a Second Language

Organic Chemistry as a Second Language Second Semester Topics

63,99 €

inkl. gesetzl. MwSt., Versandkostenfrei


Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

12.03.2024

Verlag

John Wiley & Sons Inc

Seitenzahl

576

Maße (L/B/H)

25,4/20,2/1,8 cm

Gewicht

925 g

Auflage

6th edition

Sprache

Englisch

ISBN

978-1-119-83705-3

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

12.03.2024

Verlag

John Wiley & Sons Inc

Seitenzahl

576

Maße (L/B/H)

25,4/20,2/1,8 cm

Gewicht

925 g

Auflage

6th edition

Sprache

Englisch

ISBN

978-1-119-83705-3

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: gpsr@libri.de

Noch keine Bewertungen vorhanden

Verfassen Sie die erste Bewertung zu diesem Artikel

Helfen Sie anderen Kundinnen und Kunden durch Ihre Meinung.

Kundinnen und Kunden meinen

Bewertungen (0)

  • Produktbild: Organic Chemistry as a Second Language
  • Contents

    Chapter 1 Aromaticity 1

    1.1 Introduction to Aromatic Compounds 1

    1.2 Nomenclature of Aromatic Compounds 2

    1.3 Criteria for Aromaticity 6

    1.4 Lone Pairs 9

    End-of-Chapter Problems 11

    Chapter 2 IR Spectroscopy 14

    2.1 Vibrational Excitation 14

    2.2 IR Spectra 16

    2.3 Wavenumber 16

    2.4 Signal Intensity 21

    2.5 Signal Shape 22

    2.6 Analyzing an IR Spectrum 29

    End-of-Chapter Problems 36

    Chapter 3 NMR Spectroscopy 39

    3.1 Chemical Equivalence 39

    3.2 Chemical Shift (Benchmark Values) 42

    3.3 Integration 47

    3.4 Multiplicity 50

    3.5 Pattern Recognition 52

    3.6 Complex Splitting 54

    3.7 No Splitting 55

    3.8 Hydrogen Deficiency Index (Degrees of Unsaturation) 56

    3.9 Analyzing a Proton NMR Spectrum 59

    3.10 13 C NMR Spectroscopy 63

    End-of-Chapter Problems 65

    Chapter 4 Electrophilic Aromatic Substitution 78

    4.1 Halogenation and the Role of Lewis Acids 79

    4.2 Nitration 83

    4.3 Friedel-Crafts Alkylation and Acylation 85

    4.4 Sulfonation 92

    4.5 Activation and Deactivation 96

    4.6 Directing Effects 98

    4.7 Identifying Activators and Deactivators 107

    4.8 Predicting and Exploiting Steric Effects 117

    4.9 Synthesis Strategies 124

    End-of-Chapter Problems 129

    Chapter 5 Nucleophilic Aromatic Substitution 134

    5.1 Criteria for Nucleophilic Aromatic Substitution 134

    5.2 S N Ar Mechanism 136

    5.3 Elimination-Addition 142

    5.4 Mechanism Strategies 148

    End-of-Chapter Problems 151

    Chapter 6 Ketones and Aldehydes 154

    6.1 Preparation of Ketones and Aldehydes 154

    6.2 Stability and Reactivity of C===O Bonds 157

    6.3 H-Nucleophiles 159

    6.4 O-Nucleophiles 164

    6.5 S-Nucleophiles 174

    6.6 N-Nucleophiles 176

    6.7 C-Nucleophiles 184

    6.8 Exceptions to the Rule 193

    6.9 How to Approach Synthesis Problems 197

    End-of-Chapter Problems 203

    Chapter 7 Carboxylic Acid Derivatives 207

    7.1 Reactivity of Carboxylic Acid Derivatives 207

    7.2 General Rules 208

    7.3 Acid Halides 212

    7.4 Acid Anhydrides 220

    7.5 Esters 222

    7.6 Amides and Nitriles 231

    7.7 Synthesis Problems 240

    End-of-Chapter Problems 247

    Chapter 8 Enols and Enolates 253

    8.1 Alpha Protons 253

    8.2 Keto-Enol Tautomerism 255

    8.3 Reactions Involving Enols 259

    8.4 Making Enolates 262

    8.5 Haloform Reaction 265

    8.6 Alkylation of Enolates 268

    8.7 Aldol Reactions 272

    8.8 Claisen Condensation 278

    8.9 Decarboxylation 285

    8.10 Michael Reactions 292

    End-of-Chapter Problems 299

    Chapter 9 Amines 303

    9.1 Nucleophilicity and Basicity of Amines 303

    9.2 Preparation of Amines Through S N 2 Reactions 305

    9.3 Preparation of Amines Through Reductive Amination 308

    9.4 Acylation of Amines 313

    9.5 Reactions of Amines with Nitrous Acid 316

    9.6 Aromatic Diazonium Salts 319

    End-of-Chapter Problems 322

    Chapter 10 Diels-alder Reactions 325

    10.1 Introduction and Mechanism 325

    10.2 The Dienophile 328

    10.3 The Diene 329

    10.4 Other Pericyclic Reactions 335

    End-of-Chapter Problems 336

    Detailed Solutions S-1

    Index I-1