Vor Ort
Merkzettel Warenkorb
Produktbild: Infrared Spectroscopy of Symmetric and Spherical Top Molecules for Space Observation, Volume 2

Infrared Spectroscopy of Symmetric and Spherical Top Molecules for Space Observation, Volume 2

197,99 €

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

07.10.2021

Verlag

John Wiley & Sons

Seitenzahl

318

Maße (L/B/H)

24/16,1/2,2 cm

Gewicht

645 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-78630-652-4

Beschreibung

Produktdetails

Einband

Gebundene Ausgabe

Erscheinungsdatum

07.10.2021

Verlag

John Wiley & Sons

Seitenzahl

318

Maße (L/B/H)

24/16,1/2,2 cm

Gewicht

645 g

Auflage

1. Auflage

Sprache

Englisch

ISBN

978-1-78630-652-4

Herstelleradresse

Libri GmbH
Europaallee 1
36244 Bad Hersfeld
DE

Email: GPSR Kontakt

Noch keine Bewertungen vorhanden

Verfassen Sie die erste Bewertung zu diesem Artikel

Helfen Sie anderen Kundinnen und Kunden durch Ihre Meinung.

Kundinnen und Kunden meinen

Bewertungen (0)
Die Leseprobe wird geladen.
  • Produktbild: Infrared Spectroscopy of Symmetric and Spherical Top Molecules for Space Observation, Volume 2
  • Foreword ix
    Pierre DROSSART
     
    Preface xi
     
    Chapter 1. IR Spectra in Space Observation 1
     
    1.1. Introduction 1
     
    1.2. Fourier transform spectroscopy 7
     
    1.2.1. Principle of IR spectrum acquisition by interferometry 9
     
    1.2.2. Design and operation of a long path difference interferometer 11
     
    1.2.3. FTIR absorption spectroscopy in matrices 14
     
    1.2.4. LIF and DR IR-IR spectroscopies in matrices 21
     
    1.3. Resonant cavity laser absorption spectroscopy 26
     
    1.3.1. Intracavity laser absorption spectroscopy (ICLAS) 30
     
    1.3.2. Cavity ring-down spectroscopy (CRDS) 33
     
    1.3.3. Frequency comb spectroscopy (FCS) 38
     
    1.4. Spectroscopy for space observation 43
     
    1.4.1. Spectroscopic ellipsometry for space observation 43
     
    1.4.2. Space-borne spectroscopy 56
     
    1.4.3. LIDAR spectroscopy for space observation 60
     
    1.5. Conclusion 64
     
    1.6. Appendices 64
     
    1.6.1. Appendix 1: Measurement distortion and data processing 64
     
    Chapter 2. Interactions Between a Molecule and Its Solid Environment 71
     
    2.1. Introduction 72
     
    2.2. Active molecule - solid environment system 74
     
    2.2.1. Binary interaction energy 74
     
    2.2.2. Dispersion-repulsion contribution 76
     
    2.2.3. Electrostatic contribution 76
     
    2.2.4. Induction contribution 78
     
    2.3. Two-center expansion of the term 79
     
    2.4. Conclusion 81
     
    2.5. Appendices 82
     
    2.5.1. Appendix 1: Multipole moments and dipole polarizability of a molecule with respect to its fixed reference frame 82
     
    2.5.2. Appendix 2: Elements of the rotational matrix 82
     
    2.5.3. Appendix 3: Clebsch-Gordan coefficients 84
     
    Chapter 3. Nanocage of Rare Gas Matrix 87
     
    3.1. Introduction 87
     
    3.2. Rare gases in solid state 88
     
    3.3. Molecule inclusion and deformation of the doped crystal 90
     
    3.3.1. Molecule inclusion 90
     
    3.3.2. Deformation of the doped crystal 92
     
    3.3.3. NH3 in an argon matrix 95
     
    3.3.4. Renormalization of the system's Hamiltonian 96
     
    3.4. Motions of NH3 trapped in an argon matrix 97
     
    3.4.1. Vibration-inversion mode nu2 98
     
    3.4.2. Orientational motion 100
     
    3.4.3. Translational motion 106
     
    3.4.4. Orientational motion-heat bath coupling 107
     
    3.5. Infrared spectra 108
     
    3.5.1. Infrared absorption coefficient 108
     
    3.5.2. Bar spectrum 109
     
    3.5.3. Spectral profile 112
     
    3.6. Appendices 116
     
    3.6.1. Appendix 1: Normal modes of vibrations of a Bravais lattice with face centered cubic (fcc) symmetry 116
     
    3.6.2. Appendix 2: Adjustment of the weakly perturbed rotational potential energy on the basis of the rotation matrix elements 120
     
    3.6.3. Appendix 3: Expansion coefficients of the coupling between the orientation of the molecule and lattice vibrations (phonons) 121
     
    Chapter 4. Nanocages of Hydrate Clathrates 123
     
    4.1. Introduction 123
     
    4.2. The extended substitution model 124
     
    4.3. Clathrate structures 129
     
    4.4. Inclusion of a CH4 or NH3 molecule in a clathrate nanocage 131
     
    4.4.1. Inclusion model 131
     
    4.4.2. Interaction potential energy - equilibrium configuration 133
     
    4.5. System Hamiltonian and separation of movements 136
     
    4.6. Translational motion 139
     
    4.6.1. CH4 - nanocages of the sI structure 140
     
    4.6.2. NH3 - nanocages of the sI structure 141
     
    4.7. Vibrational motions 142
     
    4.7.1. CH4 - nanocages of the sI structure 143
     
    4.7.2. NH3 - nanocages of the sI structure 14