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Extended Linear Chain Compounds Volume 3

49,99 €

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

28.03.2012

Verlag

Springer Us

Seitenzahl

580

Maße (L/B/H)

22,9/15,2/3,2 cm

Gewicht

834 g

Auflage

Softcover reprint of the original 1st ed. 1983

Sprache

Englisch

ISBN

978-1-4684-4177-2

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

28.03.2012

Verlag

Springer Us

Seitenzahl

580

Maße (L/B/H)

22,9/15,2/3,2 cm

Gewicht

834 g

Auflage

Softcover reprint of the original 1st ed. 1983

Sprache

Englisch

ISBN

978-1-4684-4177-2

Herstelleradresse

Springer-Verlag KG
Sachsenplatz 4-6
1201 Wien
AT

Email: GPSR Kontakt

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  • Produktbild: Extended Linear Chain Compounds
  • Produktbild: Extended Linear Chain Compounds
  • 1. The Infinite Linear Chain Compounds Hg3-? AsF6 and Hg3-?SbF6.- 1. History and Introduction.- 2. Chemistry.- 3. Room-Temperature Structure (D Phase).- 4. Structure-Related Properties.- 4.1. Composition.- 4.2. Extrusion of Mercury.- 4.3. Thermal and Hydrolytic Decomposition.- 5. Electrical Resistivity.- 6. Low-Temperature Structure: Ordering of the Mercury Chains.- 6.1. Theoretical Considerations.- 6.2. Experimental Observations.- 7. Dynamical Properties.- 7.1. Lattice Dynamics.- 7.2. Elastic Constants.- 7.3. Specific Heat.- 8. Superconducting Properties.- 9. Electron Properties.- 9.1. De Haas-van Alphen Effect and Fermi Surface.- 9.2. Induced Torque.- 9.3. Magnetoresistance.- 9.4. Nuclear Magnetic Resonance.- 9.5. Thermoelectric Power.- 9.6. Optical Reflectance.- 10. Summary.- Notation.- References.- 2. The Synthesis and Static Magnetic Properties of First-Row Transition-Metal Compounds with Chain Structures.- 1. Introduction.- 1.1. General Magnetic Interaction Hamiltonian.- 1.2. Isotropic Heisenberg Interaction.- 1.3. Anisotropic Heisenberg Interaction.- 1.4. The XY (or Planar Heisenberg) Interaction.- 1.5. The Ising Interaction.- 1.6. Effects of Zero-Field Splitting.- 2. Chain Compounds of Titanium.- 3. Chain Compounds of Vanadium.- 3.1. Vanadium Chain Compounds of the AVX3 Type.- 3.2. Vanadyl Chains.- 3.3. BaVS3.- 4. Chain Compounds of Chromium.- 4.1. Crystal-Field Background for the Chromium Ion.- 4.2. Additional Theoretical Considerations for Chromium Chains.- 4.3. Chromium Chain Compounds with Halide Bridges of the AMX3 Type.- 4.4. CsCrF4: An Infinite Antiferromagnetic Triple Chain.- 4.5. Poly(chromiumphosphinates).- 5. Chain Compounds of Manganese.- 5.1. An Isotropie Antiferromagnetic Linear Chain, [(CH3)4N][MnCl3].- 5.2. A Manganese Linear Chain without 0, D > 0, D/J = 0.9.- 8.4. NiCl2 · 2H2O: A Compound with J > 0, D < 0, ? D ? /J = 0.08.- 8.5. CsNiCl3: A Compound with J 0, D/J = 0.05.- 8.6. RbNiCl3: A Compound with J < 0, D < 0, D/J = 0.08.- 8.7. Ni(N2H5)2(SO4)2: A Compound with J < 0, D < 0, ? D ? / ? J ? = 9.2.- 8.8. Ni(C4O4)(C3N2H4)2(H2O)2: A Compound with D > 0, D > 4?J ?.- 9. Chain Compounds of Copper.- 9.1. Theoretical Models Applicable for Copper Chains.- 9.2. Antiferromagnetic Exchange in a Uniformly Spaced Linear Chain, Catena-di-?-chloro-bis(pyridine)copper(II).- 9.3. Ferromagnetic Exchange Coupling in the Uniformly Spaced Copper(II) Chain Compounds, Cu(DMSO)Cl2 and Cu(TMSO)Cl2.- 9.4. Alternatingly Spaced Chain Compounds.- 9.5. A Chain Compound with a Ladderlike Structure, Catena-trichlorohydraziniumcopper(II).- 9.6. A Copper Chain Compound Bridged by an Extended Pi System Ligand, Copper Pyrazine Nitrate.- 9.7. Chain Compounds without Ligand Bridges.- 10. Summary.- Notation.- References.- 3. Ferromagnetism in Linear Chains.- 1. Introduction.- 2. Background.- 3. Synthetic Strategies.- 4. Magneto-Structural Correlations in Dimeric Systems.- 5. Theoretical Predictions.- 5.1. Static Properties of the S = 1/2 Ferromagnetic Chain.- 5.2. Static Properties of the S = 1 Ferromagnetic Chain.- 6. Recent Progress in Ferromagnetic Linear Chain Systems.- 6.1. Copper(II) Salts.- 6.2. Nickel(II) Salts.- 6.3. Cobalt(II) Salts.- 6.4. Iron(II)Salts.- Notation.- References.- 4. Magnetic Resonance in Ion-Radical Organic Solids.- 1. Introduction.- 2. Triplet Spin Excitons: Dimerized Ion-Radical Stacks.- 2.1. Wurster’s Blue Per chlor ate, (TMPD)(C1O4), Revisited.- 2.2. Supermolecular Radicals: Complex TCNQ Salts.- 2.3. Charge-Transfer and ?-Bonded Dimers.- 3. Charge-Transfer Complexes with Mixed Regular Stacks.- 3.1. Paramagnetism and Ionicity of (TMPD)(TCNQ).- 3.2. Structure of Spin Excitations.- 4. NMR Studies of Ion-Radical Solids.- 4.1. Nuclear Spins as Solid-State Probes.- 4.2. Internuclear Dipolar Local Fields.- 4.3. Electronic Local Fields.- 4.4. Dimensionality of Spin Dynamics.- 5. Paramagnetism of Ion-Radical Solids.- 5.1. Organic Conductors: Susceptibility of (TTF)(TCNQ).- 5.2. EPR Linewidth of Organic Conductors.- 5.3. Random Exchange Heisenberg Antiferromagnetic Chains.- 5.4. Atomic Limit and Spin Dynamics.- 6. Discussion.- Notation.- References.- 5. Salts of 7,7,8,8-Tetracyano-p-quinodimethane with Simple and Complex Metal Cations.- 1. Introduction.- 2. Alkali and Ammonium Salts of 7,7,8,8-Tetracyano-p-quinodimethane.- 2.1. Preparation.- 2.2. Structural Investigations.- 2.3. Phase Transitions.- 2.4. Electrical Conductivity and Other Transport Properties.- 2.5. Magnetic Measurements.- 2.6. Nuclear Magnetic Resonance.- 2.7. Vibrational, Electronic, and Photoelectron Spectra.- 2.8. Pressure Effects.- 2.9. Miscellaneous.- 3. 7,7,8,8-Tetracyano-q-quinodimethane Salts of Other Simple Metal Ions.- 4. 7,7,8,8-Tetracyano-p-quinodimethane Salts of Metal Complexes and Organometallic Compounds.- 4.1. Salts Containing Main Group Metals.- 4.2. TCNQ Salts or Adducts of Transition-Metal Complexes.- 5. Applications.- 6. Summary.- Notation.- References.- 6. Linear Chain 1,2-Dithiolene Complexes.- 1. Introduction.- 2. Chemistry of the 1,2-Dithiolene Ligand and Its Linear Complexes.- 2.1. Aliphatic 1,2-Dithiolene Complexes: [M(S2C2R2)2]Z Type.- 2.2. Aromatic 1,2-Dithiolene Complexes: [M(S2Ar)2]Z Type; z= 1? and 2?.- 3. Molecular and Electronic Structures of Metal 1,2-Dithiolene Complex Molecules.- 3.1. Molecular Structures.- 3.2. Electronic Structures.- 4. Linear Chains of Metal 1,2-Dithiolene Complex Molecules.- 4.1. Structural Data.- 4.2. Magnetic Properties.- 4.3. Electrical Properties.- 5. Conclusions.- Notation.- References.- 7. The Spin-Peierls Transition.- 1. Introduction.- 1.1. Introductory Remarks.- 1.2. Background.- 2. Theory of the Spin-Peierls Transition.- 2.1. Physical Ideas and Formulations of the Problem.- 2.2. Mean-Field Results.- 2.3. Beyond Mean-Field Solutions.- 2.4. Effects of External Probes: Magnetic Field, Pressure, and NMR.- 2.5. Relationship to Regular Peierls Transition.- 3. Experimental Systems.- 3.1. Tetrathiafulvalenium Bis-Dithiolene Meta-Compounds.- 3.2. (Methylethylmorpholinium)(Bis-7,7,8,8-Tetracyano-p-quinodimethamide), MEM(TCNQ)2.- 3.3. Other Possible Spin-Peierls Systems.- 3.4. High-Magnetic-Field Experiments.- 3.5. Pressure Experiments.- 4. Conclusions and Summary.- Notation.- References.- 8. Polypyrrole: An Electrochemical Approach to Conducting Polymers.- 1. Introduction.- 2. PyrroleBlack.- 3. Electrochemical Preparation of Polypyrrole.- 4. Free-Standing Films.- 5. Electrochemical Properties of Thin Films.- 6. N-Substituted Polypyrroles.- 7. AnionVariation.- 8. Applications.- References.- 9. Compendium of Synthetic Procedures for One-Dimensional Substances.- 1. Introduction.- 2. Organic Materials.- 2.1. Electron-Donor Molecules.- 2.2. Electron-Acceptor Molecules.- 2.3. Organic Charge-Transfer Complexes.- 3. Inorganic Materials.- 3.1. Metal Dithiolenes.- 3.2. Partially Oxidized Metal-Chain Systems.- 3.3. Polymercury Cation Chain Systems.- 4. Polymeric Materials.- 4.1. Poly(sulfurnitride)[Polythiazyl],(SN)x.- 4.2. Polyacetylene, (CH)x.- 4.3. Polypyroles.- References.- 10. Structural, Magnetic, and Charge Transport Properties of Stacked Metal Chelate Complexes.- 1. Introduction.- 2. Integrated Stack Crystals.- 2.1. General Features.- 2.2. Metal Complex D+p or A?q, Organic Molecule A?q or D+p.- 2.3. Mixed-Metal Complexes.- 3. Segregated Stack Crystals, Integral Oxidation State Metal Complexes.- 3.1. General Features.- 3.2. Metal Complex Not Stacked.- 3.3. Metal Complex Stacked.- 3.4. Structurally Uncharacterized Systems.- 4. Segregated Stack Crystals, Nonintegral Oxidation State Metal Complexes.- 4.1. General Features and Methods of Characterization.- 4.2. The ?,?-Dionedioximates.- 4.3. The Porphyrins and Derivatives.- 4.4. Other Metallomacrocycles.- 5. Future Directions.- References.