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Produktbild: Extended Linear Chain Compounds

Extended Linear Chain Compounds Volume 2

49,99 €

inkl. gesetzl. MwSt., Versandkostenfrei

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

22.03.2012

Verlag

Springer Us

Seitenzahl

532

Maße (L/B/H)

22,9/15,2/2,9 cm

Gewicht

767 g

Auflage

1982

Sprache

Englisch

ISBN

978-1-4684-3934-2

Beschreibung

Produktdetails

Einband

Taschenbuch

Erscheinungsdatum

22.03.2012

Verlag

Springer Us

Seitenzahl

532

Maße (L/B/H)

22,9/15,2/2,9 cm

Gewicht

767 g

Auflage

1982

Sprache

Englisch

ISBN

978-1-4684-3934-2

Herstelleradresse

Springer-Verlag KG
Sachsenplatz 4-6
1201 Wien
AT

Email: GPSR Kontakt

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  • Produktbild: Extended Linear Chain Compounds
  • 1. An Added Dimension—Two-Dimensional Analogs of One-Dimensional Materials.- 1. Introduction—General Considerations.- 1.1. Intercalation.- 1.2. Other Properties.- 2. Carbon and Other Elemental Phases.- 2.1. Carbon.- 2.2. Sulfur and Phosphorus.- 2.3. (SN)x and (BN)x.- 3. Transition Metal Dichalcogenides and Trichalcogenides.- 3.1. Dichalcogenides.- 3.2. Trichalcogenides.- 4. Phosphates, Phosphonates, and Phosphinates.- 4.1. Metal Salts.- 4.2. Biological Chains and Layers.- 5. Silicates, Clays, and Related Substances.- 5.1. Structures Derived from Silica.- 5.2. Clays.- 6. Metal Halides, Oxyhalides, and Related Compositions.- 6.1. Halides.- 6.2. Oxyhalides.- 6.3. Ziegler–Natta Catalysts.- 7. Metal Cyanide, Macrocyclic, and Related Coordination Compounds.- 8. New Directions and Conclusions.- Notation.- Addendum.- References.- 2. The Electronic Structure of Semiconducting Polymers.- 1. Introduction.- 2. Electronic Excitations: Measurements and Concepts.- 2.1. Ground Versus Excited State Properties.- 2.2. Measured Spectra.- 2.3. Models.- 3. The Molecular Solid State.- 3.1. Structure and Molecular Dynamics.- 3.2. Comparison of Gas Phase and Solid State Spectra.- 3.3. Relaxation.- 3.4. Fluctuations.- 4. Localization and Transport.- 4.1. Figures of Merit.- 4.2. Relations between Structure and Transport.- 4.3. Doped Polymers.- 4.4. Model Calculations.- 5. Synopsis.- Notation.- References.- 3. Band Structures of One-Dimensional Inorganic, Organic, and Polymeric Conductors.- 1. Introduction.- 2. Energy Band.- 3. Band Theory.- 3.1. Linear Combination of Atomic Orbitals—Band Orbitals.- 3.2. Total Electronic Energy.- 4. Electron—Electron Repulsion and Orbital Occupancy.- 4.1. Low-Spin and High-Spin States of a Molecular Dimer.- 4.2. Metallic and Magnetic Insulating States of a Crystalline Chain.- 5. Band Structures of Some Conducting Polymer Chains.- 5.1. Conjugated Polymers.- 5.2. Polymer Chains of Transition Metal Ions.- 6. Concluding Remarks.- Notation.- References.- 4. Quasi-One-Dimensional Conductors: The Peierls Instability, Pressure and Fluctuation Effects.- 1. Introduction.- 2. Phase transitions.- 3. Phase Transitions: Theoretical Treatment.- 4. Commensurate CDW State under Pressure.- 5. Fluctuations in Quasi-One-Dimensional Conductors.- 6. Fröhlich Fluctuation Conductivity.- 7. Single-Particle versus Fluctuating Conductivity.- Notation.- References.- 5. Optical Properties of One-Dimensional Systems.- 1. Introduction.- 2. Optical Properties of Solids.- 2.1. The Complex Dielectric Function.- 2.2. Anisotropic Materials.- 2.3. Experimental Techniques.- 2.4. Physical Models for One-Dimensional Systems.- 3. The Platinum Chain Salts.- 3.1. Unoxidized Tetracyanoplatinates.- 3.2. Optical Properties of K2Pt(CN)4Br0.3·3H2O, KCP(Br).- 3.3. Optical Properties of Other Platinum Chain Systems.- 4. Linear Chain Organic Systems.- 4.1. The Simple Insulating Salts.- 4.2. The Complex Insulating Salts.- 4.3. The “Metal-Like” Compounds.- 4.4. The Tetrathiafulvalenium 7,7,8,8-Tetracyano-p-quinodimethanide, (TTF)(TCNQ) Family.- 4.5. The Radical Cation Chain Compounds.- 5. Conducting Polymers.- 5.1. Poly(sulfurnitride), (SN)x.- 5.2. Polyacetylene.- 6. Conclusion.- Notation.- References.- 6. Superstructures and Phase Transitions in One-Dimensional Inorganic and Organic Materials.- 1. Structural Changes and Phase Transitions in One-Dimensional Conductors.- 1.1. Uniform 2kF Transitions.- 1.2. Uniform 4kF and 4kF–2kF Transitions.- 2. X-Ray Diffraction Patterns of Sinusoidal Structure.- 3. 2kF Superstructures of Partially Oxidized Bis(oxalato)platinate Complexes.- 3.1. K1.81[(Pt(C2O4)2]·2H2O, ?-K-OP.- 3.2. Rb1.67[Pt(C2O4)2]·1.5H2O, Rb-OP.- 3.3. Coulomb Interaction between Pt Chains with Charge Density Waves.- 4. 4kF–2kF Transition in K1.75[Pt(CN)4]·1.5H2O, K(def)TCP.- 5. Monomer—Dimer (M-D) Transition of (Alkali Metal) (TCNQ) Complexes.- 6. Phase Transitions in N-Methyl-N-Ethylmorpholinium-bis-(7,7,8,8-tetracyano-p-quinodimethanide)(MeEtM) (TCNQ)2—A Large-U Model for 1 : 2 TCNQ Salts.- 7. High-Pressure Structures and Phase Transitions in K2[Pt(CN)4]Br0.3·3H2O, KCP(Br).- Notation.- References.- 7. X-ray, Neutron, and Electron Scattering Studies of One-Dimensional Inorganic and Organic Conductors.- 1. Introduction.- 1.1. Charge Density Waves in Electronically One-Dimensional Conductors.- 1.2. Principles of Observation of Soft Phonons and Superstructures by Structural Measurements.- 2. Structural Results in K2Pt(CN)4Br0.3·3H2O.- 3. Organic Solids—7,7,8,8-Tetracyano-p-quinodimethane (TCNQ) Charge Transfer Salts.- 3.1. Charge Density Waves in Tetrathiofulvalene (TTF) and Tetraselenafulvalene (TSeF) Charge Transfer Salts of TCNQ.- 3.2. Charge Density Waves in TCNQ Salts of Hexamethylenetetrathio- and Hexamethylenetetraselenafulvalene.- 3.3. Charge Density Waves in N-Methylphenazinuum-7,7,8,8-Tetracyano-p-quinodimethanide.- 4. Structural Results in MX3 (M = Ta, Nb; X = S, Se).- 4.1. Charge Density Waves in TaS3.- 4.2. Charge Density Waves in NbSe3.- 5. Concluding Remarks.- Notation.- References.- 8. Photoconductive Properties of Organic Assemblies and a Comparison with Dark Conductors.- 1. Introduction.- 2. Some Chemical Aspects of Charge Generation and Transport.- 3. Some Qualitative Energetics of Light-Induced Charge Generation—Comparison with Dark Conductors.- 4. Three-Dimensional versus Low-Dimensional Interactions—The Importance of Surface Area.- 5. Three-Dimensionally Ordered Systems—Anthracene.- 5.1. Thick Crystals d ?l, d ? 1/?.- 5.2. Thin Crystals.- 6. Low-Dimensional Photoconductive Systems.- 6.1. Dye-Monolayer Assemblies.- 6.2. Multilayer Dye Assemblies.- 7. From Excitons to Charge Carriers.- 8. Geminate Recombination.- 8.1. The Poole-Frenkel Effect.- 8.2. The Onsager Formalism.- 9. Charge Generation in Polymers.- 9.1. Poly(N-vinylcarbazole) and [(Poly(N-vinylcarbazole))(2,4,7-trinitro-9-fluorenone)].- 9.2. Molecularly Doped Polymers.- 9.3. Visible Sensitization of Molecularly Doped Polymers.- 10. Charge Transport.- 11. Charge Transport in Polymers.- 11.1. Poly(N-vinylcarbazole and [(Poly(N-vinylcarbazole))(2,4,7-trinitro-9-fluorenone)].- 11.2. Triphenylamine-Doped Polycarbonate.- 11.3. Triphenylamine plus N-Isopropylcarbazole-Doped Polycarbonate.- 12. Summary and Conclusions.- Notation.- References.- 9. Cation-Radical Salts of Tetrathiotetracene and Tetraselenotetracene: Synthetic Aspects and Physical Properties.- 1. Introduction.- 2. Synthesis and General Chemical and Physical Properties of Tetrathiotetracene (TTT) and Tetraselenotetracene (TSeT).- 2.1. Synthesis.- 2.2. Purification of Tetrathiotetracene (TTT) and Tetraselenotetracene (TSeT).- 2.3. General Chemical and Physical Properties.- 3. Cation–Radical Salts of Tetrathiotetracene (TTT) and Tetraselenotetracene (TSeT) with Inorganic Anions.- 3.1. Synthesis and Conducting Properties.- 3.2. Iodides of TTT.- 3.3. Optical Properties of the salts of TTT and TSeT.- 4. Complexes of Tetrathiotetracene (TIT) and Tetraselenotetracene (TSeT) with Organic and Metal–Organic Acceptors.- 5. Peierls Transition in Nonstoichiometric Series of (TTT)2 I3+? Compounds.- 5.1. Peculiarities of the Crystal Structure and Energy Spectrum of Carriers.- 5.2. The Influence of the Nonstoichiometry on the Metal-to-Insulator Transition.- 5.3. Shift of the Metal-to-Insulator Transition by Pressure.- 5.4. Discussion.- 6. Peierls-Type Transition in the Isostructural Salts (TSeT)2C1 and (TSeT)2Br.- 6.1. Peculiarities of the Crystal Structure and Energy Spectrum of Carriers.- 6.2. Phase Transition and Properties of the Low-Temperature State.- 6.3. Shift of the Transition Point in (TSeT)2C1 under the Action of Magnetic Field.- 6.4. Shift of the Phase Transition under the Action of Pressures. Phase Diagram of (TSeT)2C1.- Notation.- References.- 10. Structural Aspects of One-Dimensional Conductors Based on Tetrathiafulvalene and Tetrathiatetracene.- 1. Introduction.- 2. Structures of Charge Transfer Complexes Based on Tetrathiatetracene (TTT) and Tetraselenotetracene (TSeT).- 2.1. The Crystal Structures of TTT, TSeT, and Tetratellurotetracene (TTeT).- 2.2. Halides of TSeT.- 2.3. Halides of TTT.- 2.4. Tetrathiatetracene Complexes with Metallocomplexes.- 2.5. The Internal Structure of a Conducting Stack of Cation–Radical Salts of TTT (TSeT).- 2.6. Comparison of the Geometries of the (TTT)+ Cation Radical with the TTT Neutral Molecule.- 3. Structures of Charge Transfer Complexes Based on Tetrathiafulvalene (TTF).- 3.1. Halides of TTF.- 3.2. Cation–Radical Salts of Tetramethyltetrathiafulvalene (Me4TTF).- 3.3. Complexes of Dibenzotetrathiafulvalene (DBTTF).- 4. Conclusion.- Notation.- References.- 11. Metal Complexes of Tetrathiafulvalene and Related Compounds.- 1. Introduction.- 2. Characterization.- 3. Tetrathiafulvalene Salts.- 3.1. Titanium and Tin Derivatives.- 3.2. Chromium Derivatives.- 3.3. Iron and Ruthenium Derivatives.- 3.4. Cobalt and Iridium Derivatives.- 3.5. Platinum Derivatives.- 3.6. Copper, Silver, and Gold Derivatives.- 3.7. Mercury Derivatives.- 4. Derivatives of Neutral Tetrathiafulvalene.- 5. Complexes with Metal—Sulfur Bonds.- 5.1. Platinum and Palladium Metrallotetrathiaethylenes.- 6. Metal—Tetrathialene Complexes.- 7. Bis(dithiolene) Metal—Thiacarbon Complexes.- Notation.- References.